(XBOX)zDrUnKeNMoNkEyz

Just picked up a PS5 and wanting to verify, if I link(only have Xbox account, which I believe means I wouldn’t merge,) my Series X 100% completed/all achievements etc account, to my new ps5 Warframe account, will this auto pop all trophies? I’ve read various takes on this, and trying to get solid confirmation, of exactly what needs to be done to ensure this happens. Appreciate any and all help!